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AWWA WQTC69317
- Use of Advanced NOM Characterization Methods to Trace the Fate of Organic Contaminants from a Membrane Backwash Recycle Scheme
- Conference Proceeding by American Water Works Association, 11/01/2008
- Publisher: AWWA
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Minneapolis Water Works (MWW) is currently upgrading their Fridley Filtration Plant with pressurizedmembrane ultrafiltration (UF). The 95-mgd UF facility will treat Mississippi River water that has been pretreatedby lime softening, recarbonation, coagulation, sedimentation and granular media filtration. The UFfacility will treat settled or filtered water. Spent UF and granular media backwash water will be combinedand recycled back to the softening plant (without additional treatment).A study was conducted concurrently with plant design to evaluate the operational and water quality impactsof backwash water recycle, with a particular focus on the fate of natural organic matter (NOM) that passesthrough the pretreatment processes, is retained on the UF membranes, and is displaced into the recycledbackwash water. Specific concerns of the study included the following:partitioning of colloidal and dissolved NOM fractions within the liquid and solids streams from eachtreatment step and the long-term accumulation of these fractions within the liquid stream through backwashrecycle;the potential for increased UF fouling from recycle of NOM fractions that have been demonstrated to beresponsible for low-pressure membrane fouling (biopolymer (BP) fraction, including proteins andpolysaccharides); and, disinfection byproduct(DBP) formation potential of re-chlorinated organics.Bench- and pilot-scale testing, combined with advanced NOM characterization techniques (fluorescenceexcitation emission matrix [EEM] and liquid chromatography with organic carbon detection [LC-OCD]),were used to quantify the amount of each NOM fraction present in the raw water and following eachtreatment process, from lime softening through UF, including UF and granular media filter residuals.Preliminary data show significant retention of biopolymer fractions by the hydrophilic UF membranes.Backwash combined with air scour was quite effective in removing both BP and humic fractions, especiallywhen compared to backwash alone or high pH-chlorine clean, albeit a smaller DOC removal. Thus, themembrane fouling fractions are preferentially recycled to the front of the plant, making the removal of thesefractions through the pretreatment processes more critical in order to prevent an increase in membranefouling potential. Preliminary data show that the softening step provides the most significant removal of BPand humic substances with little additional removal achieved through coagulation and sedimentation. Includes 14 references, tables, figures.